Aref A. M. ALY, Mahmoud A. GHANDOUR, Maged S. AL-FAKEH

Synthesis and characterization of transition metal coordination polymers derived from 1,4-benzenedicarboxylate and certain azoles

A series of coordination polymers of the general formula {[M(BDC)(azoles)(H2O)m].xH2O}n (where M = Co(II), Ni(II), and Cu(II); BDC = 1,4-benzenedicarboxylate; azoles = 2-aminobenzothiazole, 2-aminothiazole, and 2-amino-4-methyl-thiazole; m = 0 or 1; and x = 1 or 2) were prepared and characterized. The complexes were characterized based on elemental analysis, infrared and electronic spectral studies, magnetic measurements, molar conductance, thermal analysis, X-ray diffraction, scanning electron microscopy, and biological activity. Thermogravimetry, derivative thermogravimetry, and differential thermal analysis were used to study the thermal decomposition of the complexes. The kinetic parameters were calculated making use of the Coats-Redfern and Horowitz-Metzger equations.

Anahtar Kelimeler:

Coordination polymers, spectral studies, biological activity

Synthesis and characterization of transition metal coordination polymers derived from 1,4-benzenedicarboxylate and certain azoles

Keywords:

Coordination polymers, spectral studies, biological activity,

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Figure 7. Microbiological screening of compound 3 against F. oxysporum. a) Thiols, which are the vital constituents in the living cells and have reduction potential for disulŞde forms at or below –200 mV, may be oxidized by the studied metal complexes. b) The complexes may cause disturbances in the respiration process. c) The presence of the (C=S) group in the azole complexes might cause the action.24 −29