Priyamvada SHARMA, Riya SAİLANİ, Anita MEENA, Chandra Lata KHANDELWAL

Oxidation of crotyl alcohol by N-chloro-4-methylbenzene sulphonamide in acidic medium and in alkaline media in the presence of os(VIII) catalyst-a kinetic pathway

The kinetic pathway of oxidation of crotyl alcohol by sodium salt of N-chloro-4-methylbenzene sulphonamide (chloramine-T) in acidic and alkaline medium has been studied. The speciation of chloramine-T has been made to suggest a proper and reasonable reaction mechanism. The thermodynamic quantities such as activation energy and activation entropy are evaluated in acidic as well as in catalysed alkaline medium. An anticipated reaction mechanism has been suggested.

Keywords:

transfer reaction, reaction kinetics mechanism, osmium(VIII) catalysis, crotyl alcohol, chloramine- T,

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Bansal S, 2001, J CHEM RES, V6 .
Bishop E., 1958, TALANTA, V1, P197, DOI DOI 10.1016/0039-9140(58)80034-X
CAMPBELL MM, 1978, CHEM REV, V78, P65, DOI 10.1021/cr60311a005
Davies LJ, 2001, J MOL CATAL A-CHEM, V165, P243, DOI 10.1016/S1381-1169(00)00430-1
Dikshitulu LSA, 2009, PROGR REACTION KINET, V34, P97126, DOI [10.3184/146867809X452587s, DOI 10.3184/146867809X452587S]
Friedrich HB, 2000, TETRAHEDRON LETT, V41, P3971, DOI 10.1016/S0040-4039(00)00531-1
GRIFFITH WP, 1964, J CHEM SOC, P245, DOI 10.1039/jr9640000245
HIGUCHI T, 1968, J CHEM SOC B, P1031, DOI 10.1039/j29680001031
HUSSAIN J, 1991, J CHEM SOC DALTON, P89, DOI 10.1039/dt9910000089
Jagadeesh RV, 2008, J PHYS ORG CHEM, V21, P844, DOI 10.1002/poc.1379
Kambo N, 2004, INDIAN J CHEM A, V43 .
Kolthoff IM, 1957, VOLUMETRIC ANAL, V3 .
Latshaw M., 1925, J AM CHEM SOC, V47 .
Lee AF, 2007, J PHYS CHEM C, V111, P18844, DOI 10.1021/jp709944c
Low K, 2018, CHEM COMMUN, V54, DOI 10.1039/c8cc02012d
Meenakshi KM, 2009, E-J CHEM, V6, P545, DOI 10.1155/2009/149032
Mohan K, 2008, INDIAN J CHEM A, V47, P1226
MORRIS JC, 1948, J AM CHEM SOC, V70, P2036, DOI 10.1021/ja01186a016
Nagaraju P, 2008, CATAL COMMUN, V9, P1389, DOI 10.1016/j.catcom.2007.11.038
Puttaswamy, 2006, IND ENG CHEM RES, V45, P1563, DOI 10.1021/ie0509746
Rangappa KS, 2002, INT J CHEM KINET, V34, P49, DOI 10.1002/kin.10011
RAO VRS, 1970, TALANTA, V17, P770, DOI 10.1016/0039-9140(70)80166-7
Rosch F., 2011, RADIOCHEMISTRY RADIO .
Sailani R, 2014, B KOREAN CHEM SOC, V35, P111, DOI 10.5012/bkcs.2014.35.1.111
SAUERBRUNN RD, 1953, J AM CHEM SOC, V75, P4170, DOI 10.1021/ja01113a012
Senger HGS, 1966, J INDIAN CHEM SOC, V43
SHARMA N, 1990, TETRAHEDRON, V46, P2845 .
SHARMA N, 1992, B CHEM SOC JPN, V65, P1125, DOI 10.1246/bcsj.65.1125
Sharma P, 2020, J CHEM RES, V44, P295, DOI 10.1177/1747519819900622
Sharma P, 2018, INT J CHEM KINET, V50, P335, DOI 10.1002/kin.21162
Sharma P, 2018, TURK J CHEM, V42, P158, DOI 10.3906/kim-1701-32
Shetty M, 2004, Z NATURFORSCH A, V59, P6368
Singh G, 2011, INT J CURRENT CHEM, V2 .
Sopper FG, 1924, J CHEM SOC, DOI 10.1039/CT9242501899
Wu GM, 2006, J MEMBRANE SCI, V275, P127, DOI 10.1016/j.memsci.2005.09.012