Fluorescent sensing platform for low-cost detection of Cu2+ by coumarin derivative: DFT calculation and practical application in herbal and black tea samples

Öz A fluorogenic probe based on a coumarin-derivative for Cu2+ sensing in CH3 CN/H2 O media (v/v, 95/5, 5.0 μM) was developed and applied in real samples. 3-(4-chlorophenyl)-6,7-dihydroxy-coumarin (MCPC) probe was obtained by synthetic methodologies and identified by spectral techniques. The probe MCPC showed remarkable changes with a “turn-off” fluorogenic sensing approach for the monitoring of Cu2+ at 456 nm under an excitation wavelength of 366 nm. The response time of the probe MCPC was founded as only 1 min. The detection limit of the probe MCPC was recorded to be 1.47 nM. The binding constant and possible stoichiometric ratio (1:1) values were determined by Benesi-Hildebrand and Job’s plot systems, respectively. The mechanism of the probe MCPC with Cu2+ was further confirmed by ESI-MS and FT-IR analyses, as well as supported by theoretical calculations. Furthermore, the probe MCPC was successfully employed for the practical applications to sense Cu2+ in different herbal and black tea samples. The proposed sensing method was also verified by ICP-OES method.

Kaynakça

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Kaynak Göster

Bibtex @araştırma makalesi { tbtkchem945496, journal = {Turkish Journal of Chemistry}, issn = {1300-0527}, eissn = {1303-6130}, address = {}, publisher = {TÜBİTAK}, year = {2020}, volume = {44}, pages = {1148 - 1163}, doi = {}, title = {Fluorescent sensing platform for low-cost detection of Cu2+ by coumarin derivative: DFT calculation and practical application in herbal and black tea samples}, key = {cite}, author = {Savran, Tahir and Karagoz, Abdurrahman and Karuk Elmas, Sukriye Nihan and Aydin, Duygu and Ozen, Furkan and Koran, Kenan and Arslan, Fatma Nur and Gorgulu, Ahmet Orhan and Yilmaz, Ibrahim} }
APA Savran, T , Karagoz, A , Karuk Elmas, S , Aydin, D , Ozen, F , Koran, K , Arslan, F , Gorgulu, A , Yilmaz, I . (2020). Fluorescent sensing platform for low-cost detection of Cu2+ by coumarin derivative: DFT calculation and practical application in herbal and black tea samples . Turkish Journal of Chemistry , 44 (4) , 1148-1163 .
MLA Savran, T , Karagoz, A , Karuk Elmas, S , Aydin, D , Ozen, F , Koran, K , Arslan, F , Gorgulu, A , Yilmaz, I . "Fluorescent sensing platform for low-cost detection of Cu2+ by coumarin derivative: DFT calculation and practical application in herbal and black tea samples" . Turkish Journal of Chemistry 44 (2020 ): 1148-1163 <
Chicago Savran, T , Karagoz, A , Karuk Elmas, S , Aydin, D , Ozen, F , Koran, K , Arslan, F , Gorgulu, A , Yilmaz, I . "Fluorescent sensing platform for low-cost detection of Cu2+ by coumarin derivative: DFT calculation and practical application in herbal and black tea samples". Turkish Journal of Chemistry 44 (2020 ): 1148-1163
RIS TY - JOUR T1 - Fluorescent sensing platform for low-cost detection of Cu2+ by coumarin derivative: DFT calculation and practical application in herbal and black tea samples AU - Tahir Savran , Abdurrahman Karagoz , Sukriye Nihan Karuk Elmas , Duygu Aydin , Furkan Ozen , Kenan Koran , Fatma Nur Arslan , Ahmet Orhan Gorgulu , Ibrahim Yilmaz Y1 - 2020 PY - 2020 N1 - DO - T2 - Turkish Journal of Chemistry JF - Journal JO - JOR SP - 1148 EP - 1163 VL - 44 IS - 4 SN - 1300-0527-1303-6130 M3 - UR - Y2 - 2020 ER -
EndNote %0 Turkish Journal of Chemistry Fluorescent sensing platform for low-cost detection of Cu2+ by coumarin derivative: DFT calculation and practical application in herbal and black tea samples %A Tahir Savran , Abdurrahman Karagoz , Sukriye Nihan Karuk Elmas , Duygu Aydin , Furkan Ozen , Kenan Koran , Fatma Nur Arslan , Ahmet Orhan Gorgulu , Ibrahim Yilmaz %T Fluorescent sensing platform for low-cost detection of Cu2+ by coumarin derivative: DFT calculation and practical application in herbal and black tea samples %D 2020 %J Turkish Journal of Chemistry %P 1300-0527-1303-6130 %V 44 %N 4 %R %U
ISNAD Savran, Tahir , Karagoz, Abdurrahman , Karuk Elmas, Sukriye Nihan , Aydin, Duygu , Ozen, Furkan , Koran, Kenan , Arslan, Fatma Nur , Gorgulu, Ahmet Orhan , Yilmaz, Ibrahim . "Fluorescent sensing platform for low-cost detection of Cu2+ by coumarin derivative: DFT calculation and practical application in herbal and black tea samples". Turkish Journal of Chemistry 44 / 4 (Ağustos 2020): 1148-1163 .
AMA Savran T , Karagoz A , Karuk Elmas S , Aydin D , Ozen F , Koran K , Arslan F , Gorgulu A , Yilmaz I . Fluorescent sensing platform for low-cost detection of Cu2+ by coumarin derivative: DFT calculation and practical application in herbal and black tea samples. Turk J Chem. 2020; 44(4): 1148-1163.
Vancouver Savran T , Karagoz A , Karuk Elmas S , Aydin D , Ozen F , Koran K , Arslan F , Gorgulu A , Yilmaz I . Fluorescent sensing platform for low-cost detection of Cu2+ by coumarin derivative: DFT calculation and practical application in herbal and black tea samples. Turkish Journal of Chemistry. 2020; 44(4): 1148-1163.
IEEE T. Savran , A. Karagoz , S. Karuk Elmas , D. Aydin , F. Ozen , K. Koran , F. Arslan , A. Gorgulu ve I. Yilmaz , "Fluorescent sensing platform for low-cost detection of Cu2+ by coumarin derivative: DFT calculation and practical application in herbal and black tea samples", Turkish Journal of Chemistry, c. 44, sayı. 4, ss. 1148-1163, Ağu. 2020
  • ISSN: 1300-0527
  • Yayın Aralığı: Yılda 6 Sayı
  • Yayıncı: TÜBİTAK

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