Çisem KIRBIYIK, Burak Zafer BÜYÜKBEKAR, Mahmut KUŞ, Mustafa ERSÖZ

Enhanced uptake capacities and isosteric heats of CO2 and CH4 adsorption on spent coffee ground activated carbons loaded with metal ions

Low-cost activated carbon (AC) samples obtained from waste coffee grounds were used for CO2 and CH4adsorption. ACs were prepared by chemical activation and carbonized at three different temperatures. AC carbonizedat 800 ◦ C showed a relatively high surface area (582.92 m2 g?1) and high adsorption capacities of 2.6 mmol g?1 and1.1 mmol g?1 at 25 ◦ C for CO2 and CH4 , respectively. Adsorbent samples were prepared by loading of Fe3+ metalions onto ACs and their adsorption capacities were compared with those of nonloaded ACs. As expected, the loading ofFe3+ metal ions increased the adsorption capacities at all temperatures and the adsorption capacity of Fe3+ -loaded ACcarbonized at 800 ◦ C was 3.1 mmol g?1 for CO2 and 1.2 mmol g?1 for CH4 at 25 ◦ C. The isosteric heats of adsorptionwere calculated at 0–35 ◦ C with the range of 20–35 kJ mol?1 and 18–23 kJ mol?1 for CO2 and CH4 , respectively.According to our findings, bio-based ACs can be used as an effective and alternative adsorbent for capturing differentgas molecules.

Keywords:

Bio-based activated carbon, CO2 adsorption, CH4 adsorption, isosteric heat,

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