Effect of sonic treatment on the permeation performance of cellulose acetate membranes modified by n-SiO_2

Cellulose acetate (CA) membranes were modified by nano-silicon dioxide (n-SiO_2), and they were exposed to ultrasonic waves at a frequency of 35 kHz. The effect of sonication on their water sorption tendency and permeation capability was investigated. The characterization of the membranes was done by FTIR and SEM analysis, and the hydrophilic character of the membranes was deduced by swelling studies and contact angle (CAn) measurements. Permeation studies of the membranes were performed by using the diffusion method and theophylline was used as a model chemical in the permeation studies. The results indicated that beside the high hygroscopic property of n-SiO_2, the presence of n-SiO_2 in CA membranes did not significantly improve their hydrophilicity; however, when they were exposed to sonic waves, it was determined that the sonication effectively enhanced their water sorption capacity and permeability.

Effect of sonic treatment on the permeation performance of cellulose acetate membranes modified by n-SiO_2

Cellulose acetate (CA) membranes were modified by nano-silicon dioxide (n-SiO_2), and they were exposed to ultrasonic waves at a frequency of 35 kHz. The effect of sonication on their water sorption tendency and permeation capability was investigated. The characterization of the membranes was done by FTIR and SEM analysis, and the hydrophilic character of the membranes was deduced by swelling studies and contact angle (CAn) measurements. Permeation studies of the membranes were performed by using the diffusion method and theophylline was used as a model chemical in the permeation studies. The results indicated that beside the high hygroscopic property of n-SiO_2, the presence of n-SiO_2 in CA membranes did not significantly improve their hydrophilicity; however, when they were exposed to sonic waves, it was determined that the sonication effectively enhanced their water sorption capacity and permeability.

___

  • Conclusion
  • The hydrophilicity of CA membranes could only be improved very slightly by using n-SiO2as a hygroscopic additive. However, the application of sonic waves to CA and SiO2/CA membranes enhanced their water
  • sorption tendency and permeation capacity. Therefore, it is confirmed that sonic treatment was an effective,
  • useful method to obtain permeable CA-based membranes.
Turkish Journal of Chemistry-Cover
  • ISSN: 1300-0527
  • Yayın Aralığı: Yılda 6 Sayı
  • Yayıncı: TÜBİTAK
Sayıdaki Diğer Makaleler

Synthesis and biological evaluation of new pyridines containing imidazole moiety as antimicrobial and anticancer agents

İkhlass ABBAS, Sobhi GOMHA, Mahmoud ELAASSER, Mohammed BAUOMI

Gaseous and dissolved oxygen sensing with stabilized pyrene in ionic liquid modified electrospun slides

Özlem ÖTER, Gülhan Sabanci ŞAHİN

Redox polymerization of N-isopropylacrylamide by using hydroxylated soya oil polymer

Abdulkadir ALLI, Timur ŞANAL, Baki HAZER

Synthesis, characterization, and metal extraction studies of a new macrobicyclic ligand

Halil Zeki GÖK, Yaşar GÖK, Esra EKER

HPLC fluorescence determination of ochratoxin A utilizing a double internal standard and its application to poultry feed

Muzaffer TUNÇEL, Elif Mine Öncü KAYA, Ülkü Dilek UYSAL, Tufan GÜRAY

Ring opening and ring closure reactions of chromone-3-carboxylic acid: unexpected routes to synthesize functionalized benzoxocinones and heteroannulated pyranochromenes

Magdy Ahmed IBRAHIM, Tarik El-sayed ALI

Selective CO methanation over NiO--Al_2O_3--ZrO_2 and Co_3O_4--Al_2O_3--ZrO_2 catalysts

Filiz DEREKAYA, Derya ERMERGEN

Synthesis and electrochemistry of phthalocyanines bearing [(3,4-dimethoxybenzyl)oxy] groups

İpek ÖMEROĞLU, Zekeriya BIYIKLIOĞLU

Synthesis, structural characterization, and antimicrobial efficiency of sulfadiazine azo-azomethine dyes and their bi-homonuclear uranyl complexes for chemotherapeutic use

ABDALLA M. KHEDR, Fawaz A. SAAD

Fluorescent mono- and tetra-dansylated cavitands: synthesis and acid sensitivity

ÜMİT İŞCİ, YUNUS ZORLU, FABIENNE DUMOULIN