Deposition and characterization of Cu9S5 nanocrystals from unsymmetrical [(Hex)(Me)NC(S)NC(O)C6H3(NO2)2-3,5]2Cu(II) and [(Et)(Bu)NC(S)NC(O)C6H4-4-NO2]2Cu(II) complexes by colloidal thermolysis method

Cu9S5 nanocrystals were synthesized from unsymmetrical [(Hex)(Me)NC(S)NC(O)C6H3(NO2)2-3,5]2Cu(II) and [(Et)(Bu)NC(S)NC(O)C6H4-4-NO2]2 Cu(II) complexes by colloidal thermolysis in the presence of surfactant oleylamine. The unsymmetrical copper complexes were synthesized by the reaction of copper(II) acetate with N-[hexyl(methyl)carbamothioyl]-3,5-dinitrobenzamide and N-[ethyl(butyl)carbamothioyl]-4-nitrobenzamide. The complexes were used as single-source precursors for the preparation of Cu9S5 nanocrsytals. The Cu9S5 nanocrystals were characterized by X-ray powder diffraction and transmission electron microscopy.

Anahtar Kelimeler:

Cu9S5 nanocrystals, p-XRD, crystallites, TEM, colloidal thermolysis, thiourea derivatives

Deposition and characterization of Cu9S5 nanocrystals from unsymmetrical [(Hex)(Me)NC(S)NC(O)C6H3(NO2)2-3,5]2Cu(II) and [(Et)(Bu)NC(S)NC(O)C6H4-4-NO2]2Cu(II) complexes by colloidal thermolysis method

Keywords:

Cu9S5 nanocrystals, p-XRD, crystallites, TEM, colloidal thermolysis, thiourea derivatives,

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Monajjemi, M.; Baei, M. T.; Mollaamin, F. Russian J. Inorg. Chem. 2008, 53, 1430–1437.
Monajjemi, M.; Mahdavian, L.; Mollaamin, F.; Khaleghian, M. Russian J. Inorg. Chem. 2009, 54, 1465–1473. Zare, K.; Daroule, M.; Mollaamin, F.; Monajjemi, M. Int. J. Phys. Sci. 2011, 6, 2536–2540.
Sun, Y. G.; Xia, Y. N. Science 2002, 298, 2176–2179.
Lee, H.; Yoon, S. W.; Kim, E. J.; Park, J. Nano Lett. 2007, 7, 778–784.
Wu, Y.; Wadia, C.; Ma, W.; Sadtler, B.; Alivisatos, A. P. Nano Lett. 2008, 8, 2551–2555.
Wadia, C.; Alivisatos, A. P.; Kammen, D. M. Environ. Sci. Technol. 2009, 43, 2072–2077.
Sakamoto, T.; Sunamura, H.; Kawaura, H. Appl. Phys. Lett. 2003, 82, 3032–3034.
Chung, J. S.; Sohn, H. J. J. Power Sources 2002, 108, 226–231.
Vaughan, D. J.; Craig, J. R. Mineral Chemistry of Metal Sulfides, ed. W. B. Harland, S. O. Agrell, A. H. Cook and N. F. Hughes, Cambridge University Press, Cambridge, UK, 1978, pp. 290–292.
Fleet, M. E. Rev. Mineral. Geochem. 2006, 61, 365–420.
Koch, D. F. A.; McIntyre, R. J. Electroanal. Chem. 1976, 71, 285–296.
He, Y. B.; Polity, A.; Osterreicher, I.; Pfisterer, D.; Gregor, R.; Meyer, B. K.; Hardt, M. Phys. B, 2001, 308–310, 1069–1073.
Wang, S. Y.; Wang, W.; Lu, Z. H. Mater. Sci. Eng. B 2003, 103, 184–188.
Sartale, S. D.; Lokhande, C. D. Mater. Chem. Phys. 2000, 65, 63–67.
Hu, H.; Nair, P. K. Surf. Coat. Technol. 1996, 81, 183–189.
Kemmler, K.; Lazell, M.; O’Brien, P.; Otway, D. J.; Park, J. H.; Walsh, J. R. J. Mater. Sci.: Mater. Electron. 2002, 13, 531–535.
Moloto, M. J.; Revaprasadu, N.; O’Brien, P.; Malik, M. A. J. Mater. Sci. Mater. Electron. 2004, 15, 313–316. Arslan, H.; Fl¨ orke, U.; Kulcu, N.; Emen, M. F. J. Coord. Chem. 2006, 59, 223–228.
Binzet, G.; Arslan, H.; Fl¨ orke, U.; Kulcu, N.; Duran, N. J. Coord. Chem. 2006, 59, 1395–1406.
Bailey, R. A.; Peterson, T. R. Can. J. Chem. 1967, 45, 1135–1142.
Saeed, S.; Rashid, N.; Jones, P. G.; Ali, M.; Hussain, R. Eur. J. Med. Chem. 2010, 45, 1323–1331.
Saeed, S.; Rashid, N.; Jones, P. G.; Hussain, R.; Bhatti, M. H. Cent. Eur. J. Chem. 2010, 8, 550–558.
Saeed, S.; Rashid, N.; Jones, P. G.; Tahir, A. J. Heterocyclic. Chem. 2011, 48, 74–82.
Saeed, S.; Rashid, N.; Hussain, R.; Jones, P. G. Eur. J. Chem. 2011, 2, 77–82.
Saeed, S.; Wong, W.-T. J. Heterocyclic. Chem. 2012, 49, 580–584.
Saeed, S.; Rashid, N.; Bhatti, M. H.; Jones, P. G. Turk. J. Chem. 2010, 34, 761–770.
Saeed, S.; Rashid, N.; Ali, M.; Hussain, R.; Jones, P. G. Eur. J. Chem. 2010, 1, 221–227.
Saeed, S.; Rashid, N.; Ali, M.; Hussain, R. Eur. J. Chem. 2010, 1, 200–205.
Saeed, S.; Rashid, N.; Hussain, R.; Jasinski, J. P.; Keeley, A. C.; Khan, S. J. Coord. Chem. 2013, 66, 126–138. Saeed, S.; Hussain, R.; Ali, M. J. Heterocyclic. Chem. 2013, 50, 237–243.
Saeed, S.; Rashid, N.; Malik, M. A.; O’Brien, P.; Wong, W.-T. New J. Chem. 2013, 37, 3214–3221.
Saeed, S.; Rashid, N.; Ahmad, K. S. Turk. J. Chem. 2013, 37, 796–804.
Ke, S.-Y.; Xue, S.-J. ARKIVOC 2006, x, 63–68.
Wei, T. B.; Chen, J. C.; Wang, X. C. Synth. Commun. 1996, 26, 1147–1152.
Fregona, D.; Giovagnini, L.; Ronconi, L.; Marzano, C.; Trevisan, A.; Sitran, S.; Biondi, B.; Bordin, F. J. Inorg. Biochem. 2003, 93, 181–189.
El-Reash, G. M. A.; Taha, F. I.; Badr, G. Transition Met. Chem. 1990, 15, 116–119.
Che, D. J.; Yao, X. L.; Li, G.; Li, Y. H. J. Chem. Soc., Dalton Trans. 1998, 1853.
Richter, R.; Beyer, L.; Kaiser, J. Z. Anorg. Allg. Chem. 1980, 461, 67–73.
Beyer, L.; Hoyer, E.; Liebscher, J.; Hartmann, H. Z. Chem. 1980, 21, 81–84.
Irving, A.; Koch, K. R; Matoetoe, M. Inorg. Chim. Acta. 1993, 206, 193–198.
Koch, K. R.; Sacht, C.; Bourne, S. Inorg. Chim. Acta 1995, 232, 109–115.
Mikami, M.; Nakagawa, I.; Shimanouch, T. Spectrochim. Acta 1967, 23A, 1037–1042.
Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, 4th ed, Wiley, New York, NY, USA, 1986.
Arslan, H.; K¨ ulc¨ u, N.; Fl¨ orke, U. Trans. Metal. Chem. 2003, 28, 816–819.
¨ Ozpozan, N.; ¨ Ozpozan, T.; Arslan, H.; Karipcin, F.; K¨ ulc¨ u, N. Thermochimica Acta 1999, 336, 97–103.
¨ Ozpozan, N.; Arslan, H.; ¨ Ozpozan, T.; Merdivan, M.; K¨ ulc¨ u, N. J. Therm. Anal. Calorim. 2000, 61, 955–965. ¨ Ozpozan, N.; Arslan, H.; ¨ Ozpozan, T.; ¨ Ozdes, N.; K¨ ulc¨ u, N. Thermochimica Acta 2000, 343, 127–133.
Arslan, H. J. Therm. Anal. Calorim. 2001, 66, 399–407.
Av¸sar, G.; K¨ ulc¨ u, N.; Arslan, H. Turk. J. Chem. 2002, 26, 607–615.
Peng, Z. A.; Peng, X. J. Am. Chem. Soc. 2001, 123, 183–184.