Contribution of heterobifunctional ligands to transition metal-catalysed C--C coupling reactions

In this account the authors' latest results in C--C coupling catalysis are reviewed. First, an efficient catalytic system for the Kumada--Tamao--Corriu coupling reaction based on NHC-phosphine (NHC = N-heterocyclic carbene) nickel complexes is presented. Then the use of palladium complexes of chiral ferrocenyl NHC-phosphines in the asymmetric Suzuki--Miyaura coupling reaction is reported. High catalytic activities and moderate enantioselectivities (ee up to 46{\%}) were obtained. Chiral ferrocenyl phosphine--ethers were also tested in the asymmetric Suzuki--Miyaura reaction yielding good activities and moderate enantioselectivities (ee up to 37{\%}). Finally, the original synthesis of a ferrocenyl rhodium(III) complex and its successful use as catalyst for a C--C coupling reaction via C--H activation of 2-phenylpyridine is presented.

Contribution of heterobifunctional ligands to transition metal-catalysed C--C coupling reactions

In this account the authors' latest results in C--C coupling catalysis are reviewed. First, an efficient catalytic system for the Kumada--Tamao--Corriu coupling reaction based on NHC-phosphine (NHC = N-heterocyclic carbene) nickel complexes is presented. Then the use of palladium complexes of chiral ferrocenyl NHC-phosphines in the asymmetric Suzuki--Miyaura coupling reaction is reported. High catalytic activities and moderate enantioselectivities (ee up to 46{\%}) were obtained. Chiral ferrocenyl phosphine--ethers were also tested in the asymmetric Suzuki--Miyaura reaction yielding good activities and moderate enantioselectivities (ee up to 37{\%}). Finally, the original synthesis of a ferrocenyl rhodium(III) complex and its successful use as catalyst for a C--C coupling reaction via C--H activation of 2-phenylpyridine is presented.

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Turkish Journal of Chemistry-Cover
  • ISSN: 1300-0527
  • Yayın Aralığı: Yılda 6 Sayı
  • Yayıncı: TÜBİTAK
Sayıdaki Diğer Makaleler

New Pd(II) and Pt(II)-diaminophosphine complexes bearing cyclohexyl or isopropyl moiety: use of Pd(II) complexes as precatalyst in Mizoroki{Heck and Suzuki{Miyaura cross-coupling reactions

Akın BAYSAL, Feyyaz DURAP, Murat AYDEMİR

A simple approach to bis-spirocycles and spiroindole derivatives via greenmethods such as Fischer indolization, ring-closing metathesis, andSuzuki{Miyaura cross-coupling

Rashid ALI, Sambasivarao KOTHA

Monodisperse palladium nanoparticles supported on chemically derived graphene: highly active and reusable nanocatalysts for Suzuki{Miyaura cross-coupling reactions

Feyyaz DURAP, Önder METİN

A simple approach to bis-spirocycles and spiroindole derivatives via green methods such as Fischer indolization, ring-closing metathesis, and Suzuki--Miyaura cross-coupling

Sambasivarao KOTHA, Rashid ALI

Substituted 2-(2''-pyridyl)benzimidazole palladium(II) complexes as an efficient catalytic system for Suzuki--Miyaura cross-coupling reactions

MAHMUT ULUSOY, NURDAL ÖNCEL, Emine AYTAR

Monodisperse palladium nanoparticles supported on chemically derived graphene: highly active and reusable nanocatalysts for Suzuki--Miyaura cross-coupling reactions

Feyyaz DURAP, Önder METİN

Synthesis of new thiol-derivatized aminophosphines and their catalytic activities in C{C coupling reactions

Nermin BİRİCİK, Nermin MERİÇ, Cezmi KAYAN, Bahattin GÜMGÜM, Zeynep ÖZGEN, Sevil ŞEKER AZİZOĞLU

Palladium-catalysed Suzuki{Miyaura cross-coupling with imidazolylidene ligandssubstituted by crowded resorcinarenyl and calixarenyl units

Neslihan ŞAHİN, Dominique MATT, David SEMERIL, Eric BRENNER, Loic TOUPET, Cemal KAYA

Sonogashira reactions for the synthesis of polarized pentacene derivatives

Stephane SCHWEIZER, Guillaume ERBLAND, Philippe BISSERET, Jacques LALEVEE, Didier Le NOUEN, Nicolas BLANCHARD

Copper-free Sonogashira cross-coupling reactions catalyzed by an efficient dimericC,N-palladacycle in DMF/H2O

Kazem KARAMI, Nasrin HAGHIGHAT NAEINI