Biodegradability of degradable mulching film in a laboratory-controlled composting test

A series of degradable films was prepared, and 2 formulas of polyethylene (PE) films with the highest degradable performance were experimentally determined. These films contained 3.43% and 0.44% stearate, and were denoted as PE-3 and PE-4, respectively. Their biodegradability was studied in a laboratory-controlled composting test using ordinary PE film (OPEF) as a control. Contrast composting experiments indicated that the biodegradability of untreated samples was very low, and that the biodegradation rates of PE films after natural aging were significantly higher. FT-IR analysis showed that OPEF changed little after the composting experiment, and that PE-3 and PE-4 showed a carbonyl absorption peak at 1720 cm-1, whose intensity increased with increased composting time. Analysis of the viscometric-average molecular weight revealed that it changed little for untreated film but significantly decreased for aged films, especially PE-3, after the composting experiments.

Biodegradability of degradable mulching film in a laboratory-controlled composting test

A series of degradable films was prepared, and 2 formulas of polyethylene (PE) films with the highest degradable performance were experimentally determined. These films contained 3.43% and 0.44% stearate, and were denoted as PE-3 and PE-4, respectively. Their biodegradability was studied in a laboratory-controlled composting test using ordinary PE film (OPEF) as a control. Contrast composting experiments indicated that the biodegradability of untreated samples was very low, and that the biodegradation rates of PE films after natural aging were significantly higher. FT-IR analysis showed that OPEF changed little after the composting experiment, and that PE-3 and PE-4 showed a carbonyl absorption peak at 1720 cm-1, whose intensity increased with increased composting time. Analysis of the viscometric-average molecular weight revealed that it changed little for untreated film but significantly decreased for aged films, especially PE-3, after the composting experiments.

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  • Rauf, A.; Baloch, M. K.; Durrani, G. F. J. Chem. Soc. Pakistan. 2010, 32, 168–171.
  • Gautam, R.; Bassi, A. S.; Yanful, E. K. Appl. Biochem. Biotech. 2007, 141, 85–108.
  • Briassoulis, D.; Dejean, C. J. Polym. Environ. 2010, 18, 384–400.
  • Zhao, C. X.; He, W. Q.; Liu, S.; Yan, C. R.; Cao, S. L. J. Arg - Environ. Sci. 2011 , 30, 1616–1621.
  • He, W. Q.; Yan, C. R.; Zhao, C. X.; Chang, R. Q.; Liu, Q.; Liu, S. J. Arg - Environ. Sci. 2009, 28, 533–538.
  • Zhang, J. H.; Jiang, P. A.; Shen, Y. X.; Wang W. G.; Su H. Y. Xinjiang. Agr. Sci. 2010, 47, 1656–1659.
  • Zhang, X. Q.; Gozukara, Y.; Sangwan, P.; Gao, D.; Bateman, S. Polym. Degrad. Stabil. 2010, 95, 2309–2317.
  • Wang, Y. Z.; Yang, K. K.; Wang, X. L.; Zhou, Q.; Zheng, C. Y.; Chen, Z. F. J. Polym. Environ. 2004, 12, 7–10. Siotto, M.; Sezenna, E.; Saponaro, S.; Innocenti, F. D.; Tosin, M.; Bonomo, L.; Mezzanotte, V. J. Environ. Manage. 2012, 93, 31–37.
  • Tosun, I.; Gonullu, M. T.; Arslankaya, E., Gunay, A. Bioresource Technol. 2008, 99, 6143–6149.
  • Ganjyal, G. M.; Weber, R.; Hanna, M. A. Bioresource Technol. 2007, 98, 3176–3179.
  • Siotto, M.; Tosin, M.; Innocenti, F. D.; Mezzanotte, V. Water Air Soil Poll. 2011, 221, 245–254.
  • ASTM D6400 Standard specification for compostable plastics. ASTM: West Conshohocken. 2004.
  • ASTM D6868 Standard specification for biodegradable plastics used as coatings on paper and other compostable substrates. ASTM: West Conshohocken. 2003.
  • UNI EN 13432 Requirements for packaging recoverable through composting and biodegradation-test scheme and evaluation criteria for the final acceptance of packaging. 2002.
  • Aminabhavi, T. M.; Balundgi, R. T. Polym. Plast. Technol. Eng. 1990, 29, 235–262.
  • Scott, G.; Wiles, D. M. Biomacromolecules. 2001, 2, 615–622.
  • Grif?n, G. J. L. Polymr. Degrad. Stabil. 1994, 45, 241–247.
  • Huang, Y. Y.; Jia, X.; Li, D. Q.; Shang, J. J.; Zhang, X. M.; Wang, J.; Liu, Z. Y. J. Shihezi University. 2012, 30, 239–242.
  • Orhan, Y.; Buyukgungor, H. Int. Biodeter. Biodegr. 2000, 45, 49–55.
  • Sastry, P. K.; Satyanarayana, D.; Rao, D. V. M. J. Appl. Polym. Sci. 1998, 70, 2251–2257.
  • Khabbaz, F.; Albertsson, A. C. J. Appl. Polym. Sci. 2001, 79, 2309–2316.
  • ISO 14855-1 Determination of ultimate aerobic biodegradability of plastic materials under controlled composting conditions-Method by analysis of evolved carbon dioxide. 2004.
  • ISO 10390 Soil quality-determination of pH. 2005.
  • APHA-AWWA-WPCF 2540 E Fixed and volatile solid ignited at 550 ◦ C. 19
  • APHA-AWWA-WPCF 2540 D Total suspended solid dried at 103-105 ◦ C. 19
  • ASTM D2216 Standard test method for laboratory determination of water (moisture) content of soil and rock by mass. 1998.
  • ASTM D5373 Standard test methods for instrumental determination of carbon, hydrogen, and nitrogen in laboratory samples of coal and coke. 2002.
  • Leejarkpai, T.; Suwanmanee, U.; Rudeekit, Y.; Mungcharoen, T. Waste Manage. 2011, 31, 1153–1161.
  • Seeba, M.; Servens, C.; Pouyet, J. J.Appl. Polym. Sci. 1992, 45, 1049–1056.
Turkish Journal of Chemistry-Cover
  • ISSN: 1300-0527
  • Yayın Aralığı: Yılda 6 Sayı
  • Yayıncı: TÜBİTAK
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Synthesis, characterization, and fluorescence study of phthalhydrazidylazo derivative of an unsaturated diketone and its metal complexes

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N-functionalized benzimidazol-2-ylidene silver complexes: synthesis, characterization, and antimicrobial studies

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