A novel optical membrane with extended detection range of pH

A pH optical sensor was developed based on the use of a mixture of Malachite Green Oxalate and Bromocresol Green indicators immobilized in a triacetylcellulose membrane, which had been previously hydrolyzed. Requirements of the pH indicators were investigated, including the effects of the coupling pH, indicator ratio, and concentrations of the indicators. The pH sensor performed with a very fast response (10 s) and long term stability with no significant leaching of the dyes. The sensor had a linear response over a range of 6.6 pH units in the pH range between 0.4 and 7.0. A relative standard deviation of pH equal to 1.59% was obtained for 7 replicated pH measurements. The procedure for preparation of this optical sensor is simple, inexpensive, and rapid.

A novel optical membrane with extended detection range of pH

A pH optical sensor was developed based on the use of a mixture of Malachite Green Oxalate and Bromocresol Green indicators immobilized in a triacetylcellulose membrane, which had been previously hydrolyzed. Requirements of the pH indicators were investigated, including the effects of the coupling pH, indicator ratio, and concentrations of the indicators. The pH sensor performed with a very fast response (10 s) and long term stability with no significant leaching of the dyes. The sensor had a linear response over a range of 6.6 pH units in the pH range between 0.4 and 7.0. A relative standard deviation of pH equal to 1.59% was obtained for 7 replicated pH measurements. The procedure for preparation of this optical sensor is simple, inexpensive, and rapid.

___

  • Lindner, E.; Zwicki, T.; Bakker, E.; Lan, B. T. T.; Toth, K.; Pretsch, E. Anal. Chem. 1998, 70, 1176-1181.
  • Hisamato, H.; Tsubuku, M.; Enomoto, T.; Watanabe, K.; Kawaguchi, H.; Koike, Y.; Suzuki, K. Anal. Chem. 1996, , 3871-3878.
  • Lobnik, A.; Oehme, I.; Murkovic, I.; Wolfbeis, O. S. Anal. Chim. Acta 1998, 367, 159-165.
  • Leiner, M. J. P.; Wolfbeis, O. S.;n: O. S. Wolfbeis (Ed.), Fiber Optic Chemical Sensors and Biosensors, vol. 1, CRC Press, Boca Raton, 1991, p. 359.
  • Wolfbeis, O. S.; Rodriguez, N. V.; Werner, T. Mikrochim. Acta 1992, 108, 133-141.
  • Motellier, S.; Toulhoat, P. Anal. Chim. Acta 1993, 271, 323-329.
  • Moreno, M. C.; Jimenez, M.; Conde, C. P.; Camara, C. Anal. Chim. Acta 1990, 230, 35-40.
  • Schulman, S. G.; Shangxian, C.; Fenglian, B.; Leiner, M. J. P.; Weis, L. L.; Wolfbeis, O. S. Anal. Chim. Acta 1995, , 165-170.
  • Jones, T. P.; Porter, M. D. Anal. Chem. 1988, 60, 404-406.
  • Lam, M. H. W.; Lee, D. Y. K.; Man, K. W.; Lau, C. S. W. J. Mater. Chem. 2000, 10, 1825-1828.
  • Kosch, U.; Klimant, I.; Werner, T.; Wolfbeis, O. S. Anal. Chem. 1998, 70, 3892-3897.
  • Sotomayor, P. T.; Raimundo Jr I. M.; Zarbin, A. J. G.; Rohwedder, J. J. R.; Alves, O. L. Sens. Actuators B 2001, , 157-162.
  • Glenn, S. J.; Gullum, B. M.; Nair, R. B.; Nivens, D. A.; Murphy, C. J.; Angel, S. M. Anal. Chim. Acta 2001, 448, 8.
  • Grummt, U. W.; Pron, A.; Zagorska, M.; Lefrant, S. Anal. Chim. Acta 1997, 357, 253-259.
  • Chan, C. M.; Fung, C. S.; Wong, K. Y.; Lo, W. Analyst 1998, 123, 1843-1847.
  • Fry, D. R.; Bobbitt, D. R. Microchem. J. 2001, 69, 25-33.
  • Ertekin, K.; Alp, S.; Karapire, C.; Yenig¨ul, B.; Henden, E.; Li, S. K. I. J. Photochem. Photobiol. A 2000, 137, 161.
  • Safavi, A.; Bagheri, M. Sens. Actuators B 2003, 90, 143-150.
  • Mohr, J.; Wolfbeis, O. S. Anal. Chim. Acta 1994, 292, 41-48
  • Taib, M. N.; Andres, R.; Narayanaswamy, R. Anal. Chim. Acta 1996, 330, 31-40.
  • Lin, J.; Liu, D. Anal. Chim. Acta 2000, 408, 49-55.
  • Jones, T. P.; Porter, M. D. Anal. Chem. 1988, 60, 404-406.
  • Wang, E.; Chow, K.-F.; Kwan, V.; Chin, T.; Wong, C.; Bocarsly, A. Anal. Chim. Acta 2003, 495 45-50.
  • Makote, R.; Collinson, M. M. Anal. Chim. Acta 1999, 394, 195-200.
Turkish Journal of Chemistry-Cover
  • ISSN: 1300-0527
  • Yayın Aralığı: Yılda 6 Sayı
  • Yayıncı: TÜBİTAK
Sayıdaki Diğer Makaleler

Effect of various substituents on intramolecular 1,1-vinylboration, synthesis of 1-silacyclobutene derivatives

Ezzat KHAN, Bernd WRACKMEYER

Electrochemical impedance spectroscopic studies of the passive layer on the surface of copper as a function of potential

Amtul NASEER, Athar Yaseen KHAN

Synthesis, spectroscopic characterization, mass spectrometry, and crystal structure of N-{[(4-bromophenyl)amino]carbonothioyl}benzamide

Sohail SAEED, Naghmana RASHID, Moazzam Hussain BHATTI

Solid phase extraction of copper, nickel, and cobalt in water samples after extraction using surfactant coated alumina modified with indane-1,2,3-trione 1,2-dioxime and determination by flame atomic absorption spectrometry

Mahdi HOSSEIN, Nasser DALALI, Ali KARIMI, Kourosh DASTANRA

Synthesis and characterisations of some new 2,4-dihydro-[1,2,4]- triazol-3-one derivatives and X-ray crystal structures of 4-(3-phenylallylideneamino)-5-thiophen-2-yl-methyl-2,4-dihydro-[1,2,4]triazol-3-one

Kemal SANCAK, Yasemin ÜNVER, Canan KAZAK, Esra DÜĞDÜ, Burcu ARSLAN

Convenient synthesis and anion recognition property of acylhydrazone-based molecular tweezer receptors

Hai-Xian REN, Ming-Gen ZHAO, Ying-Jin WANG

Solid phase extraction of copper, nickel, and cobalt in water samples using surfactant coated alumina modified with indane-1,2,3-trione 1,2-dioxime and determination by flame atomic absorption spectrometry

Nasser DALALI, Mahdi HOSSEIN, Kourosh DASTANRA, Ali KARIMI

Chemistry of 2-aminoanthraquinones

Moustafa Ahmed GOUDA, Moged Ahmed BERGHOT, Alaa SHOEIB, Khaled M. ELATTAR, Abd El-Galil Mohamed KHALIL

Chemical composition and antimicrobial activity of the essential oils of mosses (Tortula muralis Hedw., Homalothecium lutescens (Hedw.) H. Rob., Hypnum cupressiforme Hedw., and Pohlia nutans (Hedw.) Lindb.) from Turkey

Osman ÜÇÜNCÜ, Tayyibe Beyza CANSU, Turan ÖZDEMİR, Şengül ALPAY KARAOĞLU, Nurettin YAYLI

Co(III) catalysed asymmetric ring-opening of epichlorohydrin by salicylaldehyde derivatives: reversal of enantioselectivity and rate acceleration on addition of $AICl_3$

Kadriye AYDIN, Stephen T. ASTLEY, Gamze KOZ, Leman KARADENİZ