Bülent KIRKAN, Belgin YOLDAŞ, M. Yunus PAMUKOĞLU

LAVANTA BİTKİSİ ÖZÜTÜ KULLANILARAK $SİNH_2@FeNP$ NANOKOMPOZİTİNİN YEŞİL SENTEZİ İLE SULU ÇÖZELTİDEN METİLEN MAVİSİNİN GİDERİMİ: DENEYSEL TASARIM YAKLAŞIMI

Bu çalışmada, lavanta bitkisi (Lavandula angustifolia) özütü kullanılarak yeşil sentez yöntemiyle sentezlenen SiNH2@FeNP nanokompoziti ile sulu çözeltiden metilen mavisi (MM) boyar maddesinin giderilmesi Box-Behnken deneysel tasarım yöntemi uygulanarak incelenmiştir. Yeni sentezlenen bu malzeme ile sulu çözeltiden metilen mavisi gideriminde adsorpsiyon sürecini etkileyen çözelti pH’ı, adsorban dozu ve başlangıç boya konsantrasyonu parametrelerinin etkisi araştırılmıştır. Elde edilen SiNH2@FeNP nanokompozitinin yapısı FTIR, SEM ve XRD teknikleri kullanılarak karakterize edilmiştir. Deney tasarımı sonuçlarından elde edilen verilere göre, pH, başlangıç metilen mavisi konsantrasyonu ve adsorban dozaj değerleri sırasıyla 10, 42,7 mg/L ve 0,5 g/L'de tutulduğunda yaklaşık %75 metilen mavisi boya giderim veriminin elde edilebileceği belirlenmiştir. Bu veriler ışığında yeşil sentez metodu ile üretilen bu nanokompozitin çevre dostu, ucuz, uygulanabilirliği kolay ve etkili bir adsorban olduğu görülmektedir.

GREEN SYNTHESIS OF $SINH_2@FENP$ NANOCOMPOSITE USING LAVENDER EXTRACT AND REMOVAL OF METHYLENE BLUE FROM AQUEOUS SOLUTION: EXPERIMENTAL DESIGN APPROACH

In this study, the removal of methylene blue (MM) dyestuff from aqueous solution with SiNH2@FeNP nanocomposite synthesized by green synthesis method using lavender plant (Lavandula angustifolia) extract was investigated by applying Box-Behnken experimental design method. The effect of solution pH, adsorbent dose and initial dye concentration parameters, which affect the adsorption process, on the removal of methylene blue from aqueous solutions with this newly synthesized material was investigated. The structure of the obtained SiNH2@FeNP nanocomposite was characterized using FTIR, SEM and XRD techniques. According to the data obtained from the experimental design results, it was determined that approximately 75% methylene blue dye removal efficiency could be obtained when pH, initial methylene blue concentration and adsorbent dosage values were kept at 10, 42.7 mg/L and 0.5 g/L, respectively.In the light of these data, it is seen that this nanocomposite produced by the green synthesis method is an environmentally friendly, inexpensive, easy to apply and effective adsorbent.

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