Farklı çapraz bağlayıcılar uygulanmış viskon yüzeyin buruşmazlık ve performans özellikleri

Viskon, keten gibi selülozik esaslı yüzeyler, kolayca buruşma eğilimi gösterirler ve bu durum kullanım sırasında istenmeyen bir özelliktir. Bu çalışmada, N-metiloldihidroksietilen üre/katalizör karışımı, modifiye dihidroksietilenüre/katalizör karışımı ve imidazolin üç farklı çapraz bağlayıcı kimyasalın uygulanması sonrasında viskon yüzeyin formaldehit miktarı, renk, kopma ve yırtılma dayanımı, elastisite modülü, yumuşaklık ve buruşmazlık değerlerine etkilerinin araştırılması amaçlanmıştır. Çapraz bağlayıcıların viskon yüzeye bağlandığı ve komşu lifler arasında çapraz bağlar oluşturduğu gözlenmiştir. Serbest formaldehit değerlerinin tüm uygulamalarda olumlu bir şekilde 75 ppm’in altında olmasına karşın, renk farkı ve sararmanın sorun olarak devam ettiği görülmüştür. Diğer bir sorun olan kopma ve yırtılma dayanımlarında, iyileşmeler elde edilmiştir. Tüm uygulamalar için düşük eğilme rijitlik değerleri ölçülürken, yüzeylerin daha yumuşak bir tutuma sahip olduğu belirlenmiştir. Aynı zamanda konsantrasyon artışları ile birlikte yüzeylerde, yüksek buruşmazlık değerleri elde edilmiştir. Çapraz bağlayıcılar arasında imidazolinin en iyi buruşmazlık değerleri verdiği tespit edilmiştir. Sonuçlar, çapraz bağlayıcıların viskon yüzeyin buruşmazlık özelliğine olumlu katkılar yaptığını göstermiştir.

Anahtar Kelimeler:

Viskon yüzey, , çapraz bağlayıcı, , buruşmazlık, buruşmazlık, fiziksel özellikler, yumuşaklık

Wrinkle recovery and performance properties of viscose surface treated with different crosslinking agents

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1. Klemm, D., Philpp, B., Heinze, T., Heinze, U., Wagenknecht, W., Comprehensive cellulose chemistry. Volume 1 fundamentals and analytical methods, Wiley-VCH Verlag GmbH, Weinheim, 1998.
2. French, A.D., Bertoniere, N.R., Thibodeaux, D.P., Triplett, B.A., Rousselle, M.A., Goynes, W.R., Edwards, J.V., Hunter, L., McAlister, D.D., Gamble, G.R., Cotton fiber chemistry and technology, CRC Press, Boca Raton, 2006.
3. Welch, C.M., Andrews, B.A.K., Ester crosslinks: A route to high performance non-formaldehyde finishing of cotton, Textile Chemist & Colorist, 21 (2), 13-17, 1989.
4. Choi, H.-M., Nonformaldehyde polymerization-crosslinking treatment of cotton fabrics for improved strength retention, Tex Res J, 62 (10), 614-618, 1992.
5. Özgüney, A.T., Ekmekçi, K.A., Bahtiyari, M.İ., Physical properties and macromolecular structure of viscose fibers, Tekst Konfeksiyon, 16 (2), 100-104, 2006.
6. Arık, B., Latest developments on crease resistance processes for cellulosic fabrics, Pam Uni J Eng Sci, 21 (7), 296-305, 2015.
7. Orhan, M., Tiritoğlu, M., Zinetbaş, G., Investigation of the effects of different type crosslinkers on viscose fabric properties, J Text Sci Eng, 26 (115), 252-262, 2019.
8. Wu, W., Yang, C.Q., Statistical analysis of the performance of the flame retardant finishing system consisting of a hydroxy-functional organophosphorus oligomer and the mixture of DMDHEU and melamine–formaldehyde resin, Polym Degrad Stabil, 85 (1), 623-632, 2004.
9. Xie, Y., Krause, A., Mai, C., Militz, H., Richter, K., Urban, K., Evans, P., Weathering of wood modified with the N-methylol compound 1, 3-dimethylol-4, 5-dihydroxyethyleneurea, Polym Degrad Stabil, 89 (2), 189-199, 2005.
10. Hsiung, H.H., Huang, H.Y., Wang, Y.H., Wang, C., Chen, J.C., Chen, C.C., Physical properties and reaction kinetics of cotton cellulose crosslinked with dimethyloldihydroxyethyleneurea–maleic acid, J Appl Polym Sci, 92 (6), 3886-3893, 2004.
11. Yang, H., Yang, C.Q., He, Q., The bonding of a hydroxy-functional organophosphorus oligomer to nylon fabric using the formaldehyde derivatives of urea and melamine as the bonding agents, Polym Degrad Stabil, 94 (6), 1023-1031, 2009.
12. Gagliardi, D., Gruntfest, I., Creasing and creaseproofing of textiles, Tex Res J, 20 (3), 180-188, 1950.
13. Lineken, E., Davis, S., Jorgensen, C., Cellulose Interactions with certain textile resins, Tex Res J, 26 (12), 940-947, 1956.
14. Stam, P.B., Poon, G.S., Spangler, M.J., Underwood, M.P., Minimum care cotton fabrics, Tex Res J, 26 (12), 960-965, 1956.
15. Cooke, T., Roth, P., Salsbury, J., Switlyk, G., Van Loo, W., Comparison of wrinkle-resistant finishes for cotton, Tex Res J, 27 (2), 150-165, 1957.
16. Dehabadi, V.A., Buschmann, H.-J., Gutmann, J.S., Durable press finishing of cotton fabrics: An overview, Tex Res J, 83 (18), 1974-1995, 2013.
17. Sharpe, G., Mallinson, P., Easy-care finishing of cellulosics, Textile finishing. Cambridge: Society of Dyers and Colourists, 337-350, 2003.
18. Hebeish, A., Nassar, F., Ibrahim, N., Islam, A., Studies of some basic aspects in easy‐care cotton finishing, II. Influence of urea pad on free formaldehyde and strength of crosslinked cotton, Die Angewandte Makromolekulare Chemie: Applied Macromolecular Chemistry and Physics, 81 (1), 95-107, 1979.
19. Frick Jr, J., Harper Jr, R., Investigations Toward Formaldehyde-Free Finishes', Tex Res J, 52 (2), 141-148, 1982.
20. McKerron, C., Focuses on formaldehyde, Chemical Week, 140 15, 1987.
21. Choi, H.-M., Kim, Y.M., Performance improvement of nonformaldehyde wrinkle resistant finished cotton fabrics treated with dialdehydes, Fiber Polym, 2 (4), 190-195, 2001.
22. Yoon, K.J., Woo, J.H., Seo, Y.S., Formaldehyde free cross-linking agents based on maleic anhydride copolymers, Fiber Polym, 4 (4), 182-187, 2003.
23. Yu, Y.H., Lee, E.S., Bang, E.S., A new catalyst for glyoxal durable press finish of cotton fabrics, Fiber Polym, 9 (6), 715-719, 2008.
24. Lee, E.S., Kim, S.I., Effect of glycols and catalysts on cotton fabrics treated with glyoxal, Fiber Polym, 5 (3), 230-233, 2004.
25. Gonzales, E.J., Benerito, R.R., Effect of the catalyst upon the physical and chemical properties of cotton cellulose finished with derivatives of ethyleneurea, Tex Res J, 35 (2), 168-178, 1965.
26. Frick Jr, J., Harper Jr, R.J., Acetals as crosslinking reagents for cotton, J Appl Polym Sci, 29 (4), 1433-1447, 1984.
27. Frick Jr, J., Harper JR, R.J., Adducts of Glyoxal and Amides as Finishing Agents for Cotton1, Tex Res J, 51 (9), 601-606, 1981.
28. Welch, C.M., Tetracarboxylic Acids as Formaldehyde-Free Durable Press Finishing Agents: Part I: Catalyst, Additive, and Durability Studies, Tex Res J, 58 (8), 480-486, 1988.
29. Andrews, B., Nonformaldehyde, D., Finishing of Cotton with Maleic and Citric Acid, Textıle Chemıst and Colorıst, 22 63-67, 1990.
30. Rowland, S.P., Welch, C.M., Brannan, M.A.F., Gallagher, D.M., Introduction of Ester Cross Links into Cotton Cellulose by a Rapid Curing Process, Tex Res J, 37 (11), 933-941, 1967.
31. Yang, C.Q., Characterizing ester crosslinkages in cotton cellulose with FT-IR photoacoustic spectroscopy, Tex Res J, 61 (5), 298-305, 1991.
32. Yang, C.Q., Wang, X., Kang, I.-S., Ester crosslinking of cotton fabric by polymeric carboxylic acids and citric acid, Tex Res J, 67 (5), 334-342, 1997.
33. Yang, C.Q., Wang, X., Formation of cyclic anhydride intermediates and esterification of cotton cellulose by multifunctional carboxylic acids: An infrared spectroscopy study, Tex Res J, 66 (9), 595-603, 1996.
34. Hashem, M., Hauser, P., Smith, B., Wrinkle recovery for cellulosic fabric by means of ionic crosslinking, Tex Res J, 73 (9), 762-766, 2003.
35. Gagliardi, D., Gruntfest, I., Creasing and crease proofing of textiles, Tex Res J, 20 (3), 180-188, 1950.
36. Yang, C.Q., Wei, W., Lickfield, G.C., Mechanical strength of durable press finished cotton fabric: Part III: Change in cellulose molecular weight, Tex Res J, 70 (10), 910-915, 2000.
37. Kim, B.-H., Jang, J., Ko, S.-W., Durable press finish of cotton fabric using malic acid as a crosslinker, Fiber Polym, 1 (2), 116-121, 2000.
38. Mortazavi, S.M., Esmailzadeh, B.P., Application of mixtures of resin finishing to achieve some physical properties on interlining cotton fabrics: I-effect of stiffening and cross-linking agents, Iran Polym J, 13 (3), 213-218, 2004.
39. Asim, F., Kausar, N., Mahmood, M., Reaction mechanism of single step fixation process of reactive printing and crease resistance finishing of cotton fabrics, Int J Text Sci, 2 (2), 26-29, 2013.
40. Ameri Dehabadi, V., Buschmann, H.J., Gutmann, J.S., Pretreatment of cotton fabrics with polyamino carboxylic acids for salt‐free dyeing of cotton with reactive dyes, Color Technol, 129 (2), 155-158, 2013.
41. Liu, C., Zhang, C., New method of fabric wrinkle measurement based on image processing, Fibres Text East Eur, 22 (103), 51-55, 2014.
42. Mamiński, M.Ł., Trzepałka, A., Auriga, R., H’Ng, P.S., Chin, K.L., Physical and mechanical properties of thin high density fiberboard bonded with 1, 3-dimethylol-4, 5-dihydroxyethyleneurea (DMDHEU), J Adhesion, 1-12, 2018.
43. Liu, J., Wang, H., Zhang, L., Sui, S., Zhang, R., Dong, C., Liu, Y., Zhu, P., Preparation, structure and performances of cross-linked regenerated cellulose fibers, Wuhan Univ J Nat Sci, 24 (1), 1-7, 2019.
44. Qi, H., Huang, Y., Ji, B., Sun, G., Qing, F.-l., Hu, C., Yan, K., Anti-crease finishing of cotton fabrics based on crosslinking of cellulose with acryloyl malic acid, Carbohydr Polym, 135 86-93, 2016.
45. Farzana, N., Haque, A., Md, A.N., Islam, M., Smriti, S.A., Siddiqa, F., Comparative enactment of formaldehyde-free and formaldehyde-based cross-linkers on cotton woven fabrics, Tekstilec, 60 (2), 2017.
46. Lao, L., Fu, L., Qi, G., Giannelis, E.P., Fan, J., Superhydrophilic wrinkle-free cotton fabrics via plasma and nanofluid treatment, ACS Appl Mater Inter, 9 (43), 38109-38116, 2017.
47. Wedin, H., Niit, E., Mansoor, Z.A., Kristinsdottir, A.R., de la Motte, H., Jönsson, C., Östlund, Å., Lindgren, C., Preparation of viscose fibres stripped of reactive dyes and wrinkle-free crosslinked cotton textile finish, J Polym Environ, 26 (9), 3603-3612, 2018.
48. Li, W., Chen, L., Li, X., Comparison of physical-mechanical and mould-proof properties of furfurylated and dmdheu-modified wood, BioResources, 14 (4), 9628-9644, 2019.
49. Litim, N., Impact of modified glyoxalic and co-polymer acrylic crosslinkers effect on the crystallinity and mechanical properties of finished cotton, J Textile Sci Eng, 9 (391), 2, 2019.
50. Bollmus, S., Beeretz, C., Militz, H., Tensile and impact bending properties of chemically modified scots pine, Forests, 11 (1), 84, 2020.
51. Ke, G., Xiao, Z., Jin, X., Yu, L., Li, J., Zhang, H., Wrinkle recovery angle enhancement and tensile strength loss of 1,2,3,4-butanetetracarboxylic acid finished lyocell fabrics, Tex Res J, 0040517520912035, 2020.
52. Yick, K.L., Cheng, K., How, Y.L., Subjective and objective evaluation of men's shirting fabrics, International Journal of Clothing Science and Technology, 7 (4), 17-29, 1995.
53. Cook, J.G., Handbook of Textile Fibres Vol. 2: Man-Made Fibres, Woodhead Publishing, Cambridge, 2009.
54. Swicofil, A.G. Viscose CV. 2018 02.01.2019]; Available from: https://www.swicofil.com/commerce/products/viscose/278/introduction.
55. Jui-Chin, C., Wei-Hua, Y., Chien-HSin, C., Cheng-Chi, C., Dyeing kinetics from a finite bath of direct dyes on DMDHEU-AA crosslinked cotton, Tex Res J, 72 (1), 55, 2002.
56. Huang, K.S., Yang, K.L., Lin, S.J., Lian, W.T., Antiwrinkle treatment of cotton fabric with a mixed sol of TEOS‐TTB/DMDHEU, J Appl Polym Sci, 106 (4), 2559-2564, 2007.
57. Orhan, M., Crease resistant effect of modified n-methyloldihydroxyethyleneurea and softeners, Tekst Konfeksiyon, 23 (2), 152-158, 2013.
58. Hashem, M., Ibrahim, N.A., El-Shafei, A., Refaie, R., Hauser, P., An eco-friendly–novel approach for attaining wrinkle–free/soft-hand cotton fabric, Carbohydr Polym, 78 (4), 690-703, 2009.
59. Wei, W., Yang, C.Q., Polymeric carboxylic acid and citric acid as a nonformaldehyde dp finish, Text Chem Col Ame Dye Rep, 32 (2), 53-57, 2000.
60. Zhang, W., Okubayashi, S., Badura, W., Bechtold, T., Fibrillation tendency of cellulosic fibers. VII. Combined effects of treatments with an alkali, crosslinking agent, and reactive dye, J Appl Polym Sci, 100 (2), 1176-1183, 2006.
61. Chen, J.C., Yao, W.H., Chen, C.H., Chen, C.C., Degree of crosslinked cotton cellulose with prereacted DMDHEU–AA, J Appl Polym Sci, 82 (7), 1580-1586, 2001.
62. Stevens, C., Smith, B., Cross-Linking of Cotton Cellulose with Ethylene Urea Derivatives Having Varying Hydrogen-Bonding Capabilities: Part I: Effects on the Physical Properties and the Hydrogen-Bonded Structure, Tex Res J, 40 (8), 749-760, 1970.
63. Franklin, W.E., Madasci, J.P., Rowland, S.P., Creasable Durable Press Cotton Fabrics By Polymerization and Crosslinking, Textile Chemist & Colorist, 8 (4), 1976.
64. Rowland, S.P., Blouin, F.A., Mason, J.S., Polymerization-crosslinking of N-methylolacrylamide in Cotton Fabric, Tex Res J, 48 (2), 73-80, 1978.
65. Shih, F.F., Bertoniere, N.R., Rowland, S.P., Polymerization-crosslinking of N-methylolmethacrylamide in cotton fabric, Tex Res J, 50 (7), 433-439, 1980.
66. Hsiung, H.-H., Chen, C.-C., Crosslinking Cotton Fabric with DMDMDHEU Using Water/Methanol Mixtures as Solvents, Tex Res J, 65 (10), 607-613, 1995.
67. Hussain, T., Ali, S., Qaiser, F., Predicting the crease recovery performance and tear strength of cotton fabric treated with modified N‐methylol dihydroxyethylene urea and polyethylene softener, Color Technol, 126 (5), 256-260, 2010.
68. Dalbaşı, E.S., Effects of causticizing on crease resistance of cellulosic woven fabrics, Tekst Konfeksiyon, 26 (1), 2016.
69. Rafique, S., Parveen, S., Ahmad, B., Hussain, T., Pigment Dyeing and Finishing of Cotton/Polyester Fabrics with a Modified Dihydroxyethyleneurea and various Softener Treatment, Life Science Journal, 11 (5), 2014.
70. AE, S., RL D, A., Postle, R., TJ, M., A statistical analysis of subjective and objective methods of evaluating fabric handle, Journal of the Textile Machinery Society of Japan, 34 (2), 39-46, 1988.
71. Pan, N., Yen, K., Zhao, S., Yang, S., A new approach to the objective evaluation of fabric handle from mechanical properties: part I: objective measure for total handle, Tex Res J, 58 (8), 438-444, 1988.
72. Mahar, T., Postle, R., Measuring and interpreting low-stress fabric mechanical and surface properties: part IV: subjective evaluation of fabric handle, Tex Res J, 59 (12), 721-733, 1989.
73. Ozcelik, G., Supuren, G., Gulumser, T., Tarakcioglu, I., A study on subjective and objective evaluation of the handle properties of shirt fabrics, Fibres Text East Eur, 16 (3), 68, 2008.
74. Sülar, V., Okur, A., Objective evaluation of fabric handle by simple measurement methods, Tex Res J, 78 (10), 856-868, 2008.
75. Ryu, H.-S., Roh, E.K., Preference and subjective evaluation of washed fabric hand using conjoint analysis, Tex Res J, 80 (20), 2167-2175, 2010.
76. Ko, Y.C., Park, J.Y., Lee, J.H., Kim, H.J., Principles of developing a softness evaluation technology for hygiene paper, Journal of Korea TAPPI, 49 (4), 184-193, 2017.
77. Fox, S.C., Li, B., Xu, D., Edgar, K.J., Regioselective esterification and etherification of cellulose: a review, Biomacromolecules, 12 (6), 1956-1972, 2011.
78. Chang, H.-L., Chen, C.-C., Crosslinking of Cotton with DMDMDHEU in the Presence of Sodium Chloride, Tex Res J, 66 (12), 803-809, 1996.
79. Chen, J.-C., Chen, C.-C., Crosslinking of Cotton Fabrics Premercerized with Different Alkalis: Part IV: Crosslinking of Normal Length Mercerized Fabrics, Tex Res J, 64 (3), 142-148, 1994.
80. Murphy, A., Margavio, M., Welch, C., All-Cotton Durable-Press Fabrics of High Strength from Slack-Mercerized, Partially Restretched Yarn: Evidence for the Separate Origins of Strength and Wrinkle-Resistance Effects in Conventional Cross-Linking Treatments for Cotton, Tex Res J, 41 (1), 22-31, 1971.