Adsorpsiyon Kolon Sisteminde Pirina Kullanılarak Ağır Metal Giderimi

Zeytinyağı üretiminden atık olarak ortaya çıkan pirina ile akü geri dönüşüm tesisi atıksuyundaki ağır metallerin giderimi sabit yataklı adsorpsiyon kolonunda incelenmiştir. Çalışmada, Aksaray Organize Sanayi bölgesinde yer alan akü geri dönüşüm tesisi atıksuyu kullanılmıştır. Ağır metal giderim çalışmasında adsorpsiyona etki eden akış hızı ve kolon yatak yüksekliği incelenmiştir. Akü geri dönüşüm atıksuyunun ham pH ve ağır metal konsantrasyonunda; maksimum giderim verimine 30 mL/dk'lık bir akış hızı ve 25 cm'lik bir kolon yüksekliğinde ulaşılmıştır. Akü geri dönüşüm atıksuyundaki Pb(II), Zn(II), Ni(II) ve Cu(II) için ortalama %98’lik giderim verimi sağlanmış olup, ağır metal adsorplanma kapasitesi 2.64 mg/g olarak hesaplanmıştır. Elde edilen sonuçlar doğrultusunda, aktifleştirilmiş pirinanın kullanımıyla akü geri dönüşüm atıksuyundaki ağır metallerin uzaklaştırılması ekonomik bir çözüm yolu sunmaktadır.

Anahtar Kelimeler:

Adsorpsiyon, Ağır metal, Akü geri dönüşüm atıksuyu, Kolon, Pirina

Heavy Metal Removal by using Olive Pomace in Adsorption Column System

The removal of heavy metals from wastewater in the battery recycling plant, which is a waste from olive oil production, was investigated in a fixed bed adsorption column. In the study, the wastewater from the battery recycling facility located in Aksaray Organized Industrial Zone was used. The effective parameters to adsorption in the study using real wastewater were examined and optimum values were determined. At studies of original pH and wastewater metal concentration; it has been determined that the maximum removal efficiency is achieved at a flow rate of 30 mL/min and height of 25 cm. The battery recycling wastewater has been treated with an average removal efficiency of 98% and a metal adsorption capacity of 2.64 mg/g for Pb (II), Zn (II), Ni (II) and Cu (II). In the direction of the results obtained, heavy metal removal using activated olive pomace offers an effective method for the economic treatment of battery recycling wastewater.

Keywords:

Adsorption, Battery recycling wastewater, Column, Heavy metal, Olive pomace,

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