N-Tipi SnS2 Yarıiletken İnce Filmlerin Hazırlanması ve Karakterizasyonu

SnS2 yarıiletken ince filmleri, kimyasal depolama yöntemi (KDY) kullanılarak 50-80oC'decam alttabanlar üzerine elde edildi. X-ışını kırınım spektrumu filmlerin amorf yapıda olduklarını göstermiştir. SnS2 filmlerin optik özelliklerini belirlemek için UV-vis spektrofotometresi kullanılmıştır. Filmlerin oda sıcaklığındaki optik geçirgenlik (%T) ve optik soğurma (A) değerleri 400-1100 nm dalga boyu aralığında belirlenmiştir. Elde edilen veriler ile filmlerin optik parametreleri olan soğurma katsayısı (?), kırılma indisi (n), sönüm katsayısı (k), reel, imajiner dielektrik sabitleri (?1, ?2) ve enerji bant aralığı (Eg) değerleri hesaplandı. Hall etkisi ölçümlerinden SnSfilmleri n-tipi iletkenliğe sahip olduğu bulunmuştur

Preparation and Characterization of N-Type SnS2 Semiconductor Thin Films

SnS2 semiconductor thin films were prepared by the chemical bath deposition (CBD) technique onto glass substrates deposited at 50-80oC. X-ray diffraction spectra of the films have shown that the films are amorphous in structure. To determine the optical properties of the SnS2 films UV-vis spectrophotometer was used. Optical transmittance (%T) and optical absorption (A) values of the films were determined in the wavelength range 400-1100 nm at room temperature. The obtained data with optical parameters of the films absorption coefficient (?), refractive index (n), extinction coefficient (k), real, imaginary dielectric constants (?1, ?) and the energy band gap (Eg) values were calculated. From the Hall effect measurement, it was found that SnS2 thin films exhibits n-type conduction

___

  • Shi C, Yang P, Yao M, Dai X, Chen Zhu., 2013. Preparation of SnS2 Thin Films by Close-Spaced Sublimation at Different Source Temperatures. Thin Solid Films, 534, 28-31.
  • Kiruthigaa G, Manoharan C, Raju C, Dhanapandian S, Thanikachalam V., 2014. Synthesis and Spectroscopic Analysis of Undoped and Zn doped SnS2 Nanostructure by Solid State Reaction Method. Materials Science in Semiconductor Processing, 26, 533- 539.
  • Khelia C, K. Boubaker, T. Ben Nasrallah, M. Amlouk, Belgacem S., 2009. Morphological and Thermal Properties of ?-SnS2 Sprayed Thin Films Using Boubaker Polynomials Expansion. Journal of Alloys and Compounds, 477, 461- 467.
  • Schlaf R, Armstrong N. R, Parkinson B. A, Pettenkofer C, Jaegermann W., 1997. Van der Waals Epitaxy of the Layered Semiconductors SnSe2 and SnS2: Morphology and Growth Modes. Surface Science, 385, 1-14.
  • Reddy, N. K, Reddy, K. T. R., 1998. Growth of Polycrystalline SnS Films by Spray Pyrolysis. Thin Solid Films, 325,4-6.
  • Koteswara Reddy N, Ramakrishna Reddy K T, Fisher G, Best R, Dutta P K., 1999. The Structural Behaviour of Layers of SnS Grown by Spray Pyrolysis. J. Phys. D: Appl. Phys, 32, 988-990.
  • Sokolov I. A.,2000. Adaptive Photodetectors: Novel Approach for Vibration Measurements. Measurement, 27, 13-9.
  • Shi W, Huo L, Wang H, Zhang H, Yang J, Wei P., 2006. Hydrothermal Growth and Gas Sensing Property of Flower Shaped SnS2 Nanostructures. Nanotechnology, 17, 2918- 2924.
  • Tan F, Qu S , Zeng X, Zhang C, Shi M, Wang Z, Jin L, Bi Y, Cao J, Wang Z, Hou Y, Teng F, Feng Z., 2010. Photovoltaic Effect of Tin Disulfide with Nanocrystalline/ Amorphous Blended Phases. Solid State Communications, 150, 58-61.
  • Seo J-W, Jang J-T, Park S-W, Kim C, Park B, Cheon J., 2008. Two-Dimensional SnS2 Nanoplates with Extraordinary High Discharge Capacity for Lithium Ion Batteries. Advanced Materials, 20, 4269-4273.
  • De D, Manongdo J, See S, Zhang V, Guloy A., 2013. Haibing Peng. High on/off Ratio Field Effect Crystalline Nanotechnology 24-025202 (6pp). Exfoliated SnS2 Nano-membranes.
  • Sanchez-Juareza A, Tiburcio-Silverb A, Ortiz Fabrication A., 2005. of SnS2/SnS Heterojunction Thin Film Diodes by Plasma- Enhanced Chemical Vapor Deposition. Thin Solid Films 480-481:452 - 456.
  • Kutchinsky J, Taboryski R, Sorensen C. B, Hansen Experimental Investigation of Supercurrent Enchancement in S-N-S Junctions by Non- Equilibrium Carrying Bound Andreev States. Physica C, 352- 4-10. P. E., 2001. Injection into Supercurrent
  • Gajendiran J, Rajendran V., 2011. Synthesis of SnS2 Nanoparticles by a Surfactant-Mediated Hydrothermal Characterization. Nanosci. Nanotechnol. 2 - 015001 (4pp). and their
  • Deshpande N.G, Sagade A. A, Gudage Y. G, Lokhande C. D., 2007. Ramphal Sharma. Growth and Characterization of Tin Disulfide (SnS2) Thin Film Deposited by Successive Ionic Layer Adsorption and Reaction (SILAR) technique. Journal of Alloys and Compounds, 436, 421-426.
  • Cheng L. L, Liu M H , Wang S. C, Wang M. X, Wang G. D, Zhou Q. Y, Chen Z. Q., 2013. Nano-flower and Nano-wall SnS2 Films Fabricated with Controllable Shape and Size by the PECVD Method. Semicond. Sci. Technol. 28-015020 (8pp).
  • Khelia C, Boubaker K, Ben Nasrallah T., Amlouk M, Belgacem S, Saadallah F, Yacoubi N., 2009. Morphological and Thermal Properties of b-SnS2 Crystals Grown by Spray Pyrolysis Technique. Journal of Crystal Growth, 311, 1032-1035.
  • George J, Valsala Kumari C. K., 1983. Growth and Characterization of Tin Disulphide Crystals Grown by Physical Vapour Transport Method. Journal of Crystal Growth, 63, 233- 238.
  • Gupta R. K, Yakuphanoglu F., 2012. Photoconductive Schottky Diode Based on Al/p-Si/SnS2/Ag Applications. Solar Energy, 86, 1539-1545.
  • Sreedevi G, Ramakrishna Reddy K. T., 2013. Dependence of Optical Properties of Chemical Bath Deposited SnS2 Films on Deposition Time. Solid State Physics, 1512, 688-689.
  • Guneri E, Ulutas C, Kirmizigul F, Altindemir G, Gode F, Gumus C., 2010. Effect of Deposition Time on Structural, Electrical, and Optical Properties of Sns Thin Films Deposited by Chemical Bath Deposition. Applied Surface Science, 257, 1189-1195.
  • Bar M, Ennaoui A, Klaer J, Saez-Araoz R, Kropp T, Weinhardt L, Heske C, Schock H. W, Fischer C. H, Lux-Steiner M. C., 2006. The Electronic [Zn(S,O)/ZnS]/CuInS Heterointerface- Impact of Post-Annealing. Chemical Physics Letters, 433, 71-74. of the
  • Panda A, Antonakos E, Liarokapis S, Bhattacharya S. Chaudhuri. S., 2007. Optical Properties of Nanocrystalline SnS2 Thin Films. S.K. Materials Research Bulletin, 42, 576-583.
  • Ramakrishna Reddy K. T, Sreedevi G, Ramyaan K , Miles R.W., 2012. Physical Properties of Nano-Crystalline SnS2 Layers Grown by Chemical Bath Deposition. Energy Procedia, 15, 340 - 346.
  • Kariper A, Güneri E, Göde F, Gümüs C, Özpozan T., 2011. The Structural, Electrical and Optical Properties of CdS Thin Films as a Function of pH. Materials Chemistry and Physics, 129, 183-188.
  • Kırmızıgül F, Güneri E, Gümüş C., 2012. Effects of different deposition conditions on the Properties of Cu2S thin films, 93,511-523.
  • Gümüş C, Ulutaş C, Esen R, Özkendir O. M, 2005. Characterization of Crystalline Mns thin Films by Chemical Bath Deposition. Thin Solid Films, 492, 1-5. Preparation and
  • Schlaf R, Armstrong N. R, Parkinson B. A, Pettenkofer C, Jaegermann W., 2007. Vander Waals Epitaxy of the Layered Semiconductors SnSe2 and SnS2: Morphology and Growth Modes. Journal of Alloys and Compounds, 436, 421-426.
  • Zhang Y. C, Du Z. N, Li S. Y, Zhang M., 2010. Novel Synthesis and High Visible Light Photocatalytic Activity of SnS2 Nanoflakes from SnCl2-2H2O and S powders. Applied Catalysis B: Environmental, 95, 153-159.
  • Geng H, Su Y, Wei H, Xu M, Wei L, Yang Z, Zhang Y., 2013. Controllable Synthesis and Photoelectric Property of Hexagonal SnS2 Nanoflakes by Triton X-100 Assisted Hydrothermal Method. MaterialsLetters, 111, 204-207.
Çukurova Üniversitesi Mühendislik-Mimarlik Fakültesi Dergisi-Cover
  • ISSN: 1019-1011
  • Yayın Aralığı: Yılda 4 Sayı
  • Başlangıç: 1986
  • Yayıncı: ÇUKUROVA ÜNİVERSİTESİ MÜHENDİSLİK FAKÜLTESİ