C.I. ASİT VİYOLET 90 METAL-KOMPLEKS BOYARMADDESİNİN SULU ORTAMLARDAN SENTETİK VE DOĞAL ZEOLİT KULLANILARAK UZAKLAŞTIRILMASI

C.I. Asit Viyolet 90 (AV 90) boyarmaddesinin gideriminde Manisa- Gördes zeoliti (M-GZ) ve sentetik bir zeolit olan moleküler elek 10 Å (Z-10A) adsorplayıcı olarak kullanılmıştır. pH 2’de en yüksek boyarmadde adsorpsiyonu Z-10A ile % 93, M-GZ ile % 73 olarak elde edilmiştir. En yüksek adsorpsiyon kapasitesi, 150 mg/L başlangıç boyarmadde derişiminde M-GZ ve Z-10A için sırasıyla 51,4 mg/g ve 1461 mg/g olarak belirlenmiştir. Sıcaklığın 303K’den 333K’e arttırılması, her iki zeolite adsorplanan boyarmadde miktarının azalmasına neden olmuştur. Adsorpsiyon denge verilerinin M-GZ için Freundlich, Z-10A için Temkin izoterm modelleri ile uyumlu olduğu belirlenmiş, boyarmadde adsorpsiyonunu en iyi tanımlayan modelin ise pseudo-ikinci derece kinetik model olduğu saptanmıştır. AV 90’ın zeolitlere adsorpsiyonunda, düşük boyarmadde derişimlerinde sadece yüzey adsorpsiyonu gerçekleşirken yüksek derişimlerde hem yüzey hemde partikül içi difüzyonun birlikte gerçekleştiği gözlemlenmiştir. Termodinamik analizler ve deneysel sonuçlar, adsorpsiyonun kendiliğinden ve ekzotermik bir proses olduğunu göstermiştir.

Anahtar Kelimeler:

Doğal ve sentetik zeolit, C.I. Asit Violet 90 metal-kompleks boyarmadde, adsorpsiyon

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