Results of the Chemical Reduction Studies of Cp*2MO2O5 by Zn at Low Ph in Aqueous Media

MeOH-H2O ortam nda, asetik asit varlçekirdekli Cp*MoO(O2CCH3)varl kristallendirilen bile ik Mo(Cp*)3( -O)6-n( -OH)n2+ .2CF3COO- formülüne sahipken, THF-dietileterden kristallendirilen bile ik [Cp*3Mo3(3-O)( -O)3( -O2CCF3)3]2[Zn2(O2CCF3)6] yap s ndad r

Anahtar Kelimeler:

Sulu orgonametallik kimya, Molibden, Okso Ligandlar, Yar m Sandaviç Kompleksler

Results of the Chemical Reduction Studies of Cp*2MO2O5 by Zn at Low Ph in Aqueous Media

Keywords:

-,

PDF

___

Sinou, D., Curr. Chem., 206, 41-59, 1999. Hanson, E. B.,
Soluble Homogeneous Catalysis , Coord. Chem. Rev. 186, 795-807, 1999.
Collange, E., Demirhan, F., Gun, J., Lev, O., Modestov, A., Poli, R., Richard, P,Saurenz D., Results of Perspectives of High Oxidation State Organomolybdenum Chemistry in Water Society of Chemistry, Special Publication No.287, Proceedings of the 20th International Conference on Organometallic Chemistry held in Corfu, Greece on 7-12 July 2002, 167-182, 2003. Royal
Poli, R., High Oxidation State Organometallic Chemistry in Aqueous Media: New Opportunities for Catalysis and Electrocatalysis , Chem. Eur:J., , 1-11, 2003.
Cousins, M., Green, H. L. M., Some Oxo- and Oxochloro-.cyclopentadienylmolybdenum Complexes , J. Chem. Soc., 1567-1573, 1964.
Herberhold, M., Kremnitz, W., Razavi, A., Schöllhorn, H., Thewalt, Dinuclear Oxo Complexes of Chromium (V) , Angew. Chem. 24, 601-602, 1985. H5)CrO2 2-A
Faller, W. J., and Y. Ma, High Oxidation State Organometallics pentamethylcyclopentadienyloxo- molybdenum (IV) and Tungsten (VI) complexes , J. Organometal. Chem, 340, 59-69,1988.
Rheingold, L. A., Harper, R. J., A Comprison of crystallographically independent molecules of bis Cp*MoO2 2, J. Organometal. Chem, 403, 335- , 1991. structures of four
Bunker, J. M., Green L. H. M., cyclopentadienylmolybdenum Chemistry. Some Oxo-, Disulphido-, and Thiohalogeno-derivates , J. Chem. Soc. Dalton, 847-851, 1981. Mono- - Oxohalogeno-, Halogeno-, Thio-
Saurenz, D., Demirhan, F., Richard, P., Poli, R.,Sitzmann, H., (VI) and Molybdenum(V) Oxo Chemistry: New Synthetic and Structural Features , Eur. J. Inorg. Chem. 1415-1424, 2002.
Demirhan , F., Richard, R. Poli, R, Oxidation Synthesis Oxo(pentamethylcyclopentadienyl)acetato complex of molybdenum(IV) O2CCH3)2, Inorg. Chim: Acta., 347, 161-166, High State and Structure of a Dinuclear Cp*Mo( -O)( - DuBois, R. M., VanDerveer, C. M., DuBois L. D., Haltiwanger, C. R., Miller, K. W., Characterization of Reactions of Hydrogen with Coordination Sülfido Ligands , 102, (25), 7456- , 1980.
Demirhan, F., Richard, R. Poli, R, unpublished observation. Bottomly, F., Chen, J., Preston, F., K., Thompson, C. R., Preparation and Properties of Cluster C5Me5)MoO O)6-nCl2, J. Am. Chem. Soc:,116(18), 7989- , 1994. ( - and ( -C5Me5)Mo3( -OH)n((
Sing, B., Long, R. J., Biani, F.F., Gatteschi, D.,Stavropoulos, P., Catalytic of Species Involved in Oxidation of Hydrocarbons under Gif-Type Conditions , 7030-7047, 1997. Iron/Zinc-Containing J. Am. Chem. Soc:,
Demirhan, F., Gun, J., Lev, O., Modestov, A., Poli, R., Richard, P., High Oxidation State Aqueous Structure of an oxo-centered Cp*Mov Trinuclear cation by Chemical reduction of Cp2*Mo2O5, J. Am. Chem. Soc:, Dalton Trans. 2109-2111, 2002. Richens, T. D.,
Ions Wiley, Chichester, pp 259-336, 1997.
The Chemistry of Aqua